1 - 17-1 CHAPTER 17 EQUILIBRIUM: THE EXTENT OF CHEMICAL...

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Unformatted text preview: 17-1 CHAPTER 17 EQUILIBRIUM: THE EXTENT OF CHEMICAL REACTIONS 17.1 If the rate of the forward reaction exceeds the rate of reverse reaction, products are formed faster than they are consumed. The change in reaction conditions results in more products and less reactants. A change in reaction conditions can result from a change in concentration or a change in temperature. If concentration changes, product concentration increases while reactant concentration decreases, but the Kc remains unchanged because the ratio of products and reactants remains the same. If the increase in the forward rate is due to a change in temperature, the rate of the reverse reaction also increases. The equilibrium ratio of product concentration to reactant concentration is no longer the same. Since the rate of the forward reaction increases more than the rate of the reverse reaction, Kc increases (numerator, [products], is larger and denominator, [reactants], is smaller). Kc = products reactants 17.2 The faster the rate and greater the yield, the more useful the reaction will be to the manufacturing process. 17.3 A system at equilibrium continues to be very dynamic at the molecular level. Reactant molecules continue to form ...
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