2008 Ochem II Exam 1

2008 Ochem II Exam 1 - . " ' ii . ,~ . , " 'Fn...

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. . . . ~" General InstructionS . ,~ . ~- , J i; " ' Chemistry) 153 " Exam 1', lOOpts .; - " '}ii 'Fn : c .. : 'WednesdaY,}at:luaty 3~, 200~" ':,' " ',' ••• J , '. ~ ,.' L Write your name Oil' thispage~ .. ' - ~. ',. ... .,' 2. Check for a total of 10 pages (inoluding thiS one andthr~ attbe~d)' ' 3. , There should bet> questions + extra credit.questions. _- ~) ::".~ -';:/'.:: " 4. Sign theattendan'cesheet as it oito~lates;;' . " , .:. ", :. '; .: 5. Keep YQllrex~m'flaton the des.ktn'ft9I~fafYQlJ~"· ',:,,:'.: r, ..' . 6,. The Iastsheeto{tlle ,exam is blank and can beU$~ asscratcb'~pef/ ' . , . , ' . .,'.;: . '., Sh6W yo~~ Work,:Be.B.pecuICWiih-Y~ur AnSWets:and:Write~iihlY '. 'Good- Luck, ,., ..... . ':. :·i· . . . ' '. " . When thee~am return~d-tYOur exams~~~- MiI'·~·.oo, page i. ,', ~ ~, " . '" ,,;'" . '; ., .... :' . ".,.: . .:. , . , ", ..... , .. ' " ' ~ : . ... '.< -.- .' '" .' . . ,;,: " ··'t ',:- -TO;-;"- ,"-1 . ,':,'-. .~ '.: ,':" ,:.~~:.: ". ...... " ::. ' , . ~ ~. ': •••• , " .... '.!, ".X .' " " . ~.,~. ..' '. :;'" :':'.'~, ~ .-;. ' ",! .1: . "'. ~'" ".i : " '. " . :', ~ ! ;" " "".," " : .. , .':'. . .-": ,". '., , , - . . . ,r' -. . ~. ",' -: . .'. ~:. "',;, , .' . .... '.,' " ,:;.,·f··. :.,.' '. .' ~ .,' " : :'.' ." '. ~ " ' . - '. . " ~ ,,',.'-:" ~ .. ','- . '.~: " :';, .,.~" ", " . ." ~ . .' ~ . '.' , '. . . ,. ' ': ~ .:. ~~ , '<': . . c '.' " '~~ ,.... ~' : " ,'., ~". ":" , :", . ... . " , . .. ., . ~ . . '- . " ,' . . ... ,' .... _' . . .... .- ,'," '.,,' . ':: ,,; -. "'" ',: ~: ~,.J:' ~'. . ", : - !:. ~ ,t-:":::. r... . ~. './ - ;. ~.- .': .' " - ~' . :\ ':'",:\ , .',', . ~. ! ~ " -.' :. -,.'. " , ";: . ,~ " ' , : , ,~':. . '" ~., ., ~ ' : ~ , . '. ,"" ' . . • '. -I : . .. .:. . . ;' ': . . . . ,.: . ' •.
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\ c ', . . , " ~ . t . (1(»). Pill jn ~ correct term foreacbofthefollowing definitions. " ; ,; I ~). A su~~ittlePt that ext~~ds ~njugation bytyson~nce . Q)"TypeQfbond vibratiQn~hat gives reHahleabsorptions in the IF. ______________ _ , ,,,' .:- ~., : '.\.' i :~, I' , :,:. ' • . , ·cj .. lntern~~ ,standard used .in 'It NMR . . ;:::. - \ I j:-' , ~ di'(kn~kltetmrefertiJ~'~J-~~ n~m;r pf peaks ina IH ,'NMR , . .' sign'a! '" .• :i <" •. ". c. "ej- Geri.efal' for cH;~p~t6ns adjacent to' a stereocenter , . ::' ; , ". ~.' I .,~. (to)Muj~.Choice.Markthe l~ttetatiSw:et(A~B. Cor DJ f6teach question in the blank to the left. o ,.~~ c: "~~if 'Bl ..Jl. .. """"'" Q )l.CI o 0 D) II ~OCH~ .i. , .,:' C) -CN . ... ,~ .,' D) ~OH '; ",j:' :j,:~. ' .. '·',,:-,.f r, ,."-::','.n.:, ,;., ,'" .c· ~ .. "., _. .~_ ,~~s.i~_" .":;',.,_ ", _ ;!~, " -H.:' !:~'. , .' 4.th~ number of Iiri~$ln the ~11 NMR $ignal for the underlined hydrogen in~ ,"::':::;t/F%~~'i;:i;:/}':;'~;~~:'{~;:1 . (bi~) ~"$'.' " .••• C)- '1. . ... ~) 1 I ,,~ '. . . C):. t . . l" D) d
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',-',:-i ':.". ' "::' ... 3; a) (8) Lidocaine (MW234) is a local anesthetic and an ~tiarrhythmiC agentus¢d tb,tr~it;~earL<·.;:~· ." attack victims~ The compound gives the analysis' below. Determine the molecular fOl1Tlula~" .
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2008 Ochem II Exam 1 - . &quot; ' ii . ,~ . , &quot; 'Fn...

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