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1aa3-2012-tut8-q - tertiary butyl group 7 Draw the Newman...

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CHEMISTRY 1AA3 Week of March 5, 2012 TUTORIAL PROBLEM SET 8 ______________________________________________________________________________ Page 1 of 2 1. Draw line structures for all of the structural isomers that satisfy the molecular formula C 4 H 6 . 2. The formula C 4 H 8 Br 2 represents a substituted form of what class of molecule: (i) alkane (ii) alkene (iii) alkyne (iv) cycloalkene (v) cycloalkane 3. Name the following compounds according to IUPAC rules. (i) (ii) (iii) 4. Draw and name all structural isomers with the formula C 4 H 8 Cl 2 . (Hint: more than 6). 5. In the following molecule, circle the following features: (a) an alcohol (b) an amine (c) a chloro group attached to a tertiary carbon atom (d) a quaternary carbon 6. Name all of the functional groups in the antiglaucoma agent Levobunolol and circle the
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Unformatted text preview: tertiary butyl group. 7. Draw the Newman projection from carbon-A to carbon-B as indicated in Levobunolol. OH F OCH 3 O F Br Cl OH NH 2 OH NH Cl O O N H H OH A B 2 8. Styrene is the monomer used to prepare the polymer polystyrene which is used in a wide range of materials. Another name for styrene is vinylbenzene. Draw the structure of styrene. Also show the possible structures of divinylbenzene. 9. Label the carbon atoms in allyl bromide as being sp 2 or sp 3 hybridized. 10. Label the sp and sp 2 hybridized carbon atoms and any sp 3 hybridized heteroatoms in the following molecule. 11. Use the E/Z nomenclature to identify the configuration of each alkene. Br Br OCH 3 (i) (ii) (iii) (iv)...
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