rhp3 hf3p2 also contains seven and eight fold

Info iconThis preview shows page 1. Sign up to view the full content.

View Full Document Right Arrow Icon
This is the end of the preview. Sign up to access the rest of the document.

Unformatted text preview: PC16-, MP (NaC1-type, M = La, Sm, Th, U etc.) RhP3, Hf3P2 (also contains seven- and eight-fold coordination of P by M), [ ( ~ 6 - ~ ) ~ ~ ~ ( ~ ~ ) 3 ~ 6 1 - ( 4 0 ) [~~6(~~)i4(/*.-~~)~~1TaZP, Hf2P (contains P in seven-, eight-, and nine-fold coordination by MI M2P (antifluorite type (p. 118), M = Ir, Rh) Hf2P M3P (M = Ti, V, Cr, Mn, Fe, Ni, Zr, Nb, Ta) M2P (PbC12-type, M = Fe, Co, Ru) [Rh9(C0)21P]2-(41) "E. FLUCK, opics in Phosphorus Chemistry 10, 193-284 (1980). T 29H. W. KROTO, J. F. NIXON, OHNO K. and N. P. C. SIMMONS, Chem. Soc., Chem. Commun., 709 (1980). J. 30W. S . SHELDRICK, KRONER, . ZWASCHKA A . SCHMIDPETER, J. F and Angew. Chem. Int. Edn. Engl. 18, 934-5 (1979). Natunvissenschafen 59, 420 (1972). W. WICHELHAUS H. G. VON SCHNERING, and 31W. DAHLMANN H. G . VON SCHNERING, and ibid. 60, 104 (1973). et a 32J. H. WEINMAIER, SCHMIDPETER, l., Angew. Chem. In?. Edn. Engl. 18, 412 (1979); Chem. Ber. 113, 2278-90 (1980); J . A. Organometallic Chem. 185, 53-68 (1980). 33G. HUTTNER, H.-D. MULLER, FRANK, H. LORENZ, ngew. Chem. Int. Edn. Engl. 14, 705-6 (1975). A. and A 3 3aR. APPEL, . GAITZSCH F. KNOCH, ngew. Chem. Int. Edn. Engl. 24, 589-90 (1985). E and A 34J. C. BURT and G. SCHMID,. Chem. Soc., Dalton Trans., 1385-7 (1978). J 35L. MARK^ and B. MARK^, Inorg. Chim. Acta 14, L39 (1975). 36P. DAPPORTO, MIDOLLINI L. SACCONI,ngew. Chem. Int. Edn. Engl. 18, 469 (1979). S. and A A. F. ZWASCHKA, K. B. DILLON, . W . G. PLATTnd T. C. WADDINGTON, Chem. Soc., A a J. 37W. S . SHELDRICK, SCHMIDPETER, Dalton Trans., 413-8 (1981) see also Angew. Chem. Int. Edn. Engl. 18, 935-6 (1979). '*M. DI VAIRA, . MIDOLLINI L. SACCONI,. Am. Chem. S OC. 101, 1757-63 (1979). For analogous complexes in which S and J @-(q3-P3) bridges RhCo, R hNi, IrCo, and RhRh, see C. BIANCHINI, . DI VAIRA, . MELIand L. SACCONI,ngew. Chem. Inr. M A A Edn. Engl. 19, 405-6 (1980). J. and P. R. RAITHBY,. Chem. Soc., Chem. Commun., 1015-6 (1978). J 39J. M. FERNANDEZ, F. G. JOHNSON, LEWIS B. 40S. B. COLBRAN,. M. HAY,B. F. G. JOHNSON,. J. LAHOZ, LEWISand P. R. RAITHBY,. Chem. Soc., Chem. Commun., C F J. J 1766-8 (1986). 4 1J. L. VIDAL, E. WALKER,. L. PRUE'TT R. C. SCHOENING, W. R and [Rh9P(C0)21]~-. Inorg. Chem. 18, 129-36 (1979). § 72.2.5 Chemical reactivity and stereochemistry 485 Phosphorus forms binary compounds with all The P2 group is isoelectronic with ethyne (p. 932) and with N2 (pp. 414-6) and Asz. It elements except Sb, Bi and the noble gases. It has emerged as a versatile ligand with several reacts spontaneously with 0 2 and the halogens at well characterized coordination modes as shown room temperature, the mixtures rapidly reaching schematically in Fig 12.7. The first compound incandescence. Sulfur and the alkali metals also containing the PZ ligand, [(Co(C0)31~(p,r*-P2)1, react vigorously with phosphorus on warming, was isolated as a red oil in 1973 and was and the element combines directly with all metals clearly similar to the already known alkyne (except Bi, Hg, Pb) frequently with incandesand As2 complexes [ { C O (...
View Full Document

This note was uploaded on 10/12/2012 for the course CHEMISTRY CHM1040 taught by Professor Jhon during the Spring '12 term at Florida A&M.

Ask a homework question - tutors are online