107B+16+Quantum+VI

Of one electron to shield the nuclear charge from the

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Unformatted text preview: s so complex there is no mathema<cal equa<on for the solu<on The Orbital approxima<on But this separa<on of variables assumes they are independent and this <me they are not It ignores the electrosta<c interac<on between the two electrons It ignores the effect of one electron to shield the nuclear charge from the other Electron spin Spin is an intrinsic property of the electron Purely quantum mechanical effect: its not really spinning but behaves as though it is Spin quantum number analogous to l s = ½ (only value allowed) Two orienta<ons given by ms, analogous to ml Ml = ± ½, or α, β or Pauli exclusion principle No to par<cles can have the same set of quantum num...
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