hw 6 with solutions - Temple University Department of...

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Temple University - Department of Chemistry CHE 3302 - Spring 2013 Problem Set#6 Due 3/26/2013 1) Consider the hydrogenic atom. For the n=1, 2, and 3 principle quantum numbers, list the values of l, m l , and m s . What is the degeneracy for each n-value? 2) Consider the hydrogen-like atom. What is the magnitude of the orbital angular momentum and the possible values of the z-component for the 2p and 3d orbitals? 3) What are the electron configurations of Li + , F - , and Mg 2+ ? 4) What are the possible term symbols for the following electron configurations? i) 1s 2 2s 2 ii) 1s 2 2s 1 3s 1 iii) 1s 2 2s 2 2p 2 5) What are the possible term symbols for the ground state of a Chlorine atom?
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0:,';; ~ !f\r-obl4.- ~L-+,:l:l 6 - C k e 2- ~ '2- G) \} .J~ (\..::', ):::0 r'-\. ..( .=- 0 M~ =- :t~ a de.""-C-~6-L, -:-t. ~. A ) (\ -:::- 2- ...R":" 0 ) 1'Vt-<. ~ t:) ; ~~.=.t;-t . ""'" - I 0 0£. \ . ,/YI ~T..L ) I".). - - ) ) I ) '"s -- 'Z- , i o~ jLO"-.c.-r-e.-t-1 = 8 , - -, I c.-A.~) 11= ~ -IL 1-:::- 0 j f'VI.,..i:: 0 i 1'1'1)':: - 2- A ~ I . 1"'1..t -:: -,, 0 I , ~ ~ ~:: :l:- t I ) ~, . . ffl --- ~ 2--) tt1A -:: -2-, _(,0, /}"Z-.I S - z.. dC--jc~< r-e--( ':' (8 - ) ---'
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- (j) 2-) J) 2p (1 ~ 2.- ; .p::- I ; 1'#1..(::: -I J 0 I -1-( 3= l'-.J.(...l+I)ll/2.;:; - r=- ( ~. b :;. .K: ((,) -:) "f J' s) - V2. - ~ J -;'t- ;-~.= . ~ ~ 10 .J I 5 - -.J b =- M ~ = fV\ (l. l ~ ><. X I () -3'-1 T' 5 ) - ..l.~ = I. 0 S-'-I -.LIO - 3'f T. ~ ("" -: +- I) 0 (~ -::-0) - 1.0 s-Vx 10 -J'1T'~
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