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Unformatted text preview: f e.g. the 1 st order
C D 2C uC kC
t Or in one-dimension
Solid State Ionics Research Lab. C 2C
C D 2 u kC
Seoul National University Kinetics Solution of the 2nd order partial differential equation is by no means
As an example, put u 0 (i.e. no convection ) C 2C D 2 kC
One may solve the equation by Laplace transform method. Solid State Ionics Research Lab. Seoul National University Kinetics 5. Temperature-dependence of the rate-law constant
n v v Ordinary Collision Molecular
collision frequency Leading to
Chemical reaction Empirically, ln k vs. 1/T gives a straight line. ln k Ea
R k Ae Ea / RT
1/ T -Sometimes,
Solid State Ionics Research Lab. k AT ne Ea / RT
Seoul National University...
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This document was uploaded on 11/26/2013.
- Fall '13