10_HO_raising_lowering [Read-Only]

2 solve for 2 2 2 2 1 1 2 0 selection

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Unformatted text preview: m state to ∗ If If have intensity, ∝ ̂ ̂ is the dipole moment operator 0, then transition is allowed 0 , then transition is forbidden Taylor series expansion of the dipole moment operator vs displacement ⋯ where is the dipole moment at eq. and is the change in dipole moment with vibration at equilibrium. ∗ ̂ ∗ ⋯ 3 9/27/2013 for transition ∗ → ∗ ̂ ⋯ ∗ ∗ , 0 when changes ⋯ ∗ ⋯ important for infrared transitions ∗ 2 2 Transitions are allowed if → ∗ ∗ 1 ∗ 1 , , 1 or Harmonic oscillator selection rule is ∆ ⋯ ⋯ ⋯ 1 and 0 1. Two electron convicts are sitting in a jail cell together. The first one says, "What are you in for?“ The second one says, "For attempting a forbidden transition." 4...
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