Lab 12 - Measuring Enthalpy Changes

Now consider an exothermic example if a chemical

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Unformatted text preview: means that a chemical proce s s (the system) absorbed heat from the water. Since the process absorbed energy, it was endothermic. Now consider an exothermic example. If a chemical process (the system) releases heat to the water (the surroundings), the temperature of the water will increase as the water absorbs heat energy and the ΔT of the water will be positive. In Part A of the lab, you will observe temperature changes that occur as compounds dissolve in water. In Parts B and C, you will observe temperature changes that occur during chemical reactions. The reaction in Part C is a neutralization. Neutralization reactions (also known as acid- base reactions, which you will study in more detail later in the www.webassig n.net/ebooks/wsug encheml1/lab_12/manual.html 2/7 4/15/13 Lab 12 - M easur ing Enthalpy Chang es course) usually involve transfer of H+ (a proton) from one chemical species to another. For example, the reaction of acetic acid and sodium hydroxide is shown below. (3) HC2H3O2(aq) + NaOH(aq) → NaC2H3O2(aq) + H2O Strong acids, such as HCl and HNO3, react with water as shown below. (4) HCl(aq) + H2O → Cl−(aq) + H3O+(aq) (5) HNO3(aq) + H2O → NO3−(aq) + H3O+(aq) H3O+ is called the hydronium ion. Whenever strong acids are placed in water, this is the species that reacts. For example, the reaction with sodium hydroxide is shown below. (6) H3O+(aq) + NaOH(aq) → Na+(aq) + 2 H2O In these reactions, species are followed by "(aq)" to indicate that they are present in aqueous solution. This notation will be used frequently in the rest of this course. In Part D of the lab, you will observe temperature changes that occur as energy is added to water in its solid and liquid phases. Equipment 1 30 mL beaker 1 100 mL beaker 1 10 mL graduated cylinder 1 digital thermometer 4 small test tubes 1 test tube rack 1 ring stand and clamp 1 hot plate/stirrer 1 magnetic stir bar 1 deionized water squirt bottle Reagents ~2 g CaCl2(s, anydrous) ~2 g NH4NO3(s) 1 mL 1 M NaOH...
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