Modernphysicalorganicchemistry2006pg897 2 2 2 2 2 2

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2001.
2062‐2063
 
 
 
 
 PhS Heat 
 
 PhS CO2Me 
 CO2Me 
 
 
 
 
 
 Ph 
 CO2Me 
 Heat 
 CO2Me 
 
 Ph 
 
 
 
 
 
 O 
 CO
 Heat 
 
 CO2Me CO2Me 
 
 
 
 
 
 
 
 O OH 
 1 . KH 
 2. H2O 
 
 Anslyn,
Dougherty.
Modern
Physical
Organic
Chemistry.
2006;
pg
899,
921,
924.
 
 
 
 


 5.)
 Please
 provide
 a
 detailed
 FMO
 analysis
 of
 the
 following
 Diels‐Alder
 Reactions.
 
 Be
 sure
 to
 indicate
 the
 HOMO
and
LUMO
orbitals
that
are
involved
in
the
reaction
in
each
case.
 
...
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This note was uploaded on 01/24/2014 for the course CHEM 436 taught by Professor White during the Spring '08 term at University of Illinois, Urbana Champaign.

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