This preview shows page 1. Sign up to view the full content.
Unformatted text preview: with the quantities that can be measured and from those derives A(V,T), G(V,T) and other thermodynamic functions. A useful relationship from calculus (aka Maxwell’s relationship). consider a function of 2 variables, F(x,y). x and y can be V, T, or P, and F can be G, S, U, H, A etc. We have: dF = F(x+dx, y+dy) – F(x,y) = A(x,y) dx + B(x,y) dy = (∂F/∂x) dx + (∂F/∂y) dy A(x,y) = (∂F/∂x) is the partial derivative of F(x,y) with respect to x, that is when it is calculated, all other variables (y in this case) are kept constant. One can also use the notation A(x,y) = (∂F/∂x)y to emphasize that y is kept constant. We will be using this kind of notation in thermodynamics because we need to specify which variable we are working with. Both A(x,y) and B(x,y) are functions of x and y themselves. Consider the partial derivative (∂A/∂y)x...
View
Full
Document
This note was uploaded on 02/13/2014 for the course CH 353M taught by Professor Lim during the Spring '08 term at University of Texas at Austin.
 Spring '08
 LIM
 Physical chemistry, pH

Click to edit the document details