HW 2 key_F07

HW 2 key_F07 - number corresponding to the compound's relative rank in the blank below the structure(8 pt 1 4 Show how you would synthesize the

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Chemistry 223 HW 2_key September 7, 2007 1. Write the formula of the product and give the structure of the intermediates A through F in the following synthesis of Trans-1-cyclohexyl-2-methoxycyclohexane. (Hint: you need to write 7 structures for full credit) (21pt) A = B = OH Br C = D = MgBr E = O OH F = O - Na + OCH 3 Trans-1-cyclohexyl-2-methoxycyclohexane Where MCPBA= M eta- C hloro P eroxy B enzoic A cid = Cl c O O-O-H 2. Explain the mechanism of this reaction using electron pushing arrows . (8 pt) CH 3 CH 2 O-H + Na-OH CH 3 CH 2 O-Na + H 2 O CH 3 CH 2 O - Na + + CH 3 CH 2 CH 2 _ Br CH 3 CH 2 OCH 2 CH 2 CH 3 + NaBr 3. Rank the following groups of compounds from most acidic (1) to least acidic (4). Place the
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Unformatted text preview: number corresponding to the compound's relative rank in the blank below the structure. (8 pt) 1 4. Show how you would synthesize the following compound using an acid chloride or an ester. Use retrosynthesis analysis. (7 pts) Retrosyntrhesis analysis CH 3 OH O O MgBr 2 CH 3 O-+ MgBr H 3 O + Synthesis O O 1) 2 2) H 3 O + MgBr CH 3 OH + O H 5. Name the alcohol bellow according to IUPAC rules: (4 pts) CH 3 HO CH 3 H 3 C 2-methyl-2-pentanol 2...
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This note was uploaded on 04/08/2008 for the course CHEM 223 taught by Professor Chahoua during the Fall '07 term at Wake Forest.

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HW 2 key_F07 - number corresponding to the compound's relative rank in the blank below the structure(8 pt 1 4 Show how you would synthesize the

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