Ch15 - 15-1 PCl5 PCl3 + Cl2 0.8 0.3 reactants kf E -0.2...

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1 -1.2 -0.7 0.3 0.8 -6 -4 -2 0 2 4 6 reactants products kf E extent of reaction 15-1 PCl 5 PCl 3 + Cl 2 rate = k f [PCl 5 ] 15-2 PCl 5 PCl 3 + Cl 2 rate = k b [PCl 3 ][Cl 2 ] -1.2 -0.7 0.3 0.8 -6 -4 4 6 reactants products kb E extent of reaction 15-3 PCl 5 PCl 3 + Cl 2 0 0.02 0.04 0.06 0.08 0.1 0.12 0246 time, s pressure [PCl5] [PCl3] [Cl2] T = 500 K k f = 1.5 s -1 k b = 1.4 x 10 -5 M -1 s -1
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2 15-4 PCl 5 PCl 3 + Cl 2 T = 150 K k f = 1.5 s -1 k b = 3.8 M -1 s -1 0 0.02 0.04 0.06 0.08 0.1 0.12 0246 time, s pressure [PCl5] [PCl3] [Cl2] 15-5 PCl 5 PCl 3 + Cl 2 T = 150 K k f = 1.5 s -1 k b = 3.8 M -1 s -1 0 0.02 0.04 0.06 0.08 0.1 0.12 time, s [PCl5] [PCl3] [Cl2] 15-6 PCl 5 PCl 3 + Cl 2 T = 150 K k f = 1.5 s -1 k b = 3.8 M -1 s -1 0 0.04 0.08 0.12 0.16 0123456 time, s [PCl5] [PCl3] [Cl2]
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3 15-7 PCl 5 PCl 3 + Cl 2 T = 150 K k f = 1.5 s -1 k b = 3.8 M -1 s -1 0 0.04 0.08 0.12 0.16 0123456 time, s pressure [PCl5] [PCl3] [Cl2] [PCl5] [PCl3] [Cl2] 15-8 PCl 5 PCl 3 + Cl 2 0 0.2 0.4 0.6 0.8 1 1.2 time, s [PCl5], atm or Q Pi = 1.1 atm Q Pi = 0 Q 15-9 0 0.2 0.4 0.6 0.8 1 1.2 0246 time, s [PCl5] [PCl3] [Cl2] P PCl5,i = 1.0 atm Added 0.2 atm PCl 5
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4 15-10 0 0.2 0.4 0.6 0.8 1 1.2 0246 time, s pressure [PCl5] [PCl3] [Cl2] Q P PCl5,i = 1.0 atm Added 0.2 atm PCl 5 15-11 0 0.2 0.4 0.6 0.8 1 1.2 time, s [PCl5] [PCl3] [Cl2] Q Added 0.30 atm Cl 2 Adding products to an equilibrium system 15-12 0 0.5 1 1.5 2 2.5
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This note was uploaded on 04/07/2008 for the course CHEM 002 taught by Professor Ryan during the Spring '08 term at Marquette.

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Ch15 - 15-1 PCl5 PCl3 + Cl2 0.8 0.3 reactants kf E -0.2...

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