34007usingthebi

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Unformatted text preview: Chart.AbbreviationsinLegendrepresenttheabbreviatednameofthegroups performingtheexperiment.       1:TheresultsoftheGCtestingfromthevariousgroupsareincludedintheSupplementaryInformationsectionunderTables1and2.TheGC resultsfromthecommercialstartingproductsareincludedinTables3and4(alsointheSIsection).TheaverageBorneol ­Isoborneolcorrection factorRffortheGCusedwas1.05787;theRfofCamphortoIsoborneolwas1.03948. 5   MPVPercentConversionofReactantsto Product 1 0.9 PercentConversion 0.8 0.7 CMWP 0.6 0.5 CCEB 0.4 0.3 NMJ 0.2 0.1 0 0 20 40 60 Time(minutes) 80 100 120  Figure4:PercentConversionvs.Time,withlegenddescribinggroups.  Discussion  WhenNaBH4wasusedtoreducetheisoborneol,therewasaminuteamountofobserved camphorintheproductmixture,whichinsinuatedthatasmallamountofproducthad,infact, experiencedthereversereactiontobecomereactant.However,bycomparingtheratiosoftheaverage commercial observedC:Iratiosfortheexperimentwithisoborneol,itis cleartoseethatcamphorintheproductsoriginatedfromcontamination,andhadnotformedfroma reversereaction.Likewise,comparingtheB:Iratiointheborneolandthesameratiofromthethe NaBH4+Borneolexperimentyie...
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