47molsborneolto1molisoborneolwitha97conversionthereact

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Unformatted text preview: ldsasimilarconclusionwithregardstodetectedisoborneolinthose productmixes.Thus,thecombinedobservedevidencestronglysupportsthehypothesisthatthe reactionrunsunderkineticcontrolgiventhesereactionconditions.  IntheMPVreaction,therearevariousinterestingaspectstothedata.Inthethreecases observed,demonstratedgraphicallyinFigure3,percentconvergenceincreasesrapidlyatfirst,with considerablyreducedmomentumpastthe100minutemark,andfinallylevelingoffattheend.The significanceisthatthereactionhasreachedastateofequilibriumatthelastmoments,wherethereis nomorenetchangeofreactanttoproduct.Thisindicatesthattheratiosobservedatandpastthismark arerepresentativeofthetrueproductratio;combinedwiththeobservedlevelingoffofthepercent 6  conversiongraphinFigure4bythe100 ­minutemarkthereactionhasreachedthermodynamiccontrol undertheseconditions,levelingofftoB:Iproductratioswhoseaverageis2.34±0.07.UsingtheB:I correctionfactor,weobtainthatthereactionhadafinalmoleratioof2.47111molBorneolto1mol isoborneol.Furthermore,usingtheRfforC:I,andtheaveragevaluefor...
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