W2013CHM2311 Part 4d Notes

A aos h gos d3h e 2c3 3c2 h 2s3 3v a1 1

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Unformatted text preview: atom that approaches from the side. MO Diagrams for Planar AH3 Step 4: Determine symmetry of H SALCs. ⤷  Point group: D3h ⤷  Assign symmetry labels to the group orbitals by determining irreducible representa0ons. H GOs D3h E 2C3 3C2 σh 2S3 3σv A1’ 1 1 1 1 1 1 x2+y2, z2 A2’ 1 1 - 1 1 1 - 1 Rz E’ 2 - 1 0 2 - 1 0 (x, y) (x2- y2, xy) A1” 1 1 1 - 1 - 1 - 1 A2” 1 1 - 1 - 1 - 1 1 z E” 2 - 1 0 - 2 1 0 (Rx, Ry) (xz, yz) MO Diagrams for Planar AH3 Step 5: Determine atomic orbitals of central atom that interact with H GOs....
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