The error in the estimation of K a pK a values can be associated with the fact

The error in the estimation of k a pk a values can be

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phosphoric acid reaches equilibrium in water. The error in the estimation of K a /pK a values can be associated with the fact that the titration curve is not 100% accurate, but instead based upon the data points that we were able to put in. For example, the first and second equivalence points were identified by the place where the second derivative was equal to zero (or where the first derivative achieved a maximum value). A problem with using this point as the equivalence point is that that there may have been an even higher maximum point if we had measured the pH after adding even smaller increments of the base. For example, a solution would be to add the base in quantities of 0.1 mL instead of between 0.5 and 1.0 mL. Another possible source of error is the fact that some carbon dioxide gas may have still been present in the cola sample, consuming the added NaOH to form another type of acid (carbonic acid). No data was collected for the third K a value since the titration was ended after a pH of 10 was achieved. In conclusion, it was determined that the concentration of phosphoric acid in the cola was 4.5 X 10 -3 moles liter . Sine the cola had a pH of 2.42, phosphoric acid was determined to have a percent dissociation of 84%. This is a relatively high value, considering phosphoric acid is a weak acid. However, the high percent dissociation is due to phosphoric acid’s ability to donate three hydrogen ions in solution. Discussion Questions: 1. The true values for the K a of phosphoric acid are 7.1 X 10 -3 , 6.3 X 10 -8 , and 4.5 X 10 -13 . The values that were obtained for the first two K a values were 1.3 X 10 -3 and 1.0 X 10 -7 . There is a noticeable issue when using graphical analysis to determine the K a /pK a values. In order to determine these values we had to determine the location of the inflections points on the titration curve, or essentially where the second derivative had a value of zero. Although the inflections points were clearly visible on the graph of the derivative (the local maximums and minimums), this only represents the general region around which the actual equilibrium and half equilibrium position lie. A titration curve is based on a group of points, and the curve is not always completely smooth. Therefore the maximums and minimums on the derivative function can only represent the inflection points of the given data. Increasing the accuracy of estimation with a titration curve would involve plotting a lot more points. Adding the NaOH in 0.1 mL quantities, for example, would help achieve a far smoother curve with more concrete points. This would reduce the amount of estimation that needs to be done by the graphing program when developing the curve, and reduce the amount of estimation that needs to be done when reading the graph. 2. Degassing the cola prior to the titration was a very important step because it eliminated the risk of a side reaction that would have altered the data. The gas in the cola is carbon dioxide.
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  • Fall '12
  • SOPER
  • pH, Phosphoric acid

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