organic-2-organic-chemistry-brown-351-ch-17-carboxylic-acids-3595.pdf

Practice determine the major product for the

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PRACTICE: Determine the major product for the following reaction. PRACTICE: Determine the major product for the following reaction. PRACTICE: Determine the major product for the following reaction. PRACTICE: Determine the major product for the following reaction. ORGANIC - BROWN 8E CH. 17 - CARBOXYLIC ACIDS Page 12
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CONCEPT: SPECIFIC CARBOXYLIC ACID CONVERSIONS Synthesis of Acid Chloride: Synthesis of Amides: Dehydration of Amides: Hydrolysis of Nitriles: ORGANIC - BROWN 8E CH. 17 - CARBOXYLIC ACIDS Page 13
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CONCEPT: DECARBOXYLATION β -carbonyl carboxylic acids easily decarboxylate when heated, producing CO 2 gas. Mechanism: EXAMPLE: Predict the correct structure for the final product. ORGANIC - BROWN 8E CH. 17 - CARBOXYLIC ACIDS Page 14
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PRACTICE: Provide the mechanism for the following reaction. O O H O O ORGANIC - BROWN 8E CH. 17 - CARBOXYLIC ACIDS Page 15
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PRACTICE: Which carbonyl group will undergo decarboxylation most readily? HOOC C C C O O HO O OH O OH ORGANIC - BROWN 8E CH. 17 - CARBOXYLIC ACIDS Page 16
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