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Express the pH to two decimal places.ANSWER:CorrectThe buffer composed of 0.12of propionic acid and 9.0×10−2of its conjugate base, propionate, is made more basic through the addition of astrong base, . Therefore, the values of the weak acid and its conjugate weak base should be adjusted accordingly. The appropriateHenderson-Hasselbalch equation, using the amounts in moles, isPart CWhat is the of the buffer after the addition of 0.02of ?Express the pH to two decimal places.ANSWER:CorrectThe buffer composed of 0.12of propionic acid and 9.0×10−2of its conjugate base, propionate, is made more acid through the addition of astrong acid, . Therefore, the values of the weak acid and its conjugate weak base should be adjusted accordingly. The appropriate Henderson-Hasselbalch equation, using the amounts in moles, isProblem 17.24 CustomA buffer is prepared by adding 11.0of ammonium chloride to 230of 1.00 solution.Part ApH= 4.76pHmolmolpKapHpHpH = p+ logKa9.0×mol10−20.12molpHmolNaOH= 4.93pHmolmolNaOHpH = 4.9 + log9.0×mol+0.02mol10−20.12mol−0.02molpHmolHI= 4.59pHmolmolHIpH = 4.9 + log9.0×mol−0.02mol10−20.12mol+0.02molg(NCl)H4mLMNH3pH
4/4/15, 12:51 PMHw17-Chapter17Page 9 of 32What is the of this buffer?ANSWER:CorrectPart BWrite the net ionic equation for the reaction that occurs when a few drops of nitric acid are added to the buffer.Express your answer as a chemical equation. Identify all of the phases in your answer.ANSWER:CorrectPart CWrite the net ionic equation for the reaction that occurs when a few drops of potassium hydroxide solution are added to the buffer.Express your answer as a chemical equation. Identify all of the phases in your answer.ANSWER:Correct± Titrations CustomLearning Goal:To learn about titration types and how to calculate at different points of titration.In an acid-base titration, a titrant(solution of a base or acid) is added slowly to an analyte(solution of an acid or base). The titration is often monitored using a meter. A plot of as a function of the volume of titrant added is called a titration curve.Prior to the titration, the is determined by the concentration of the analyte. When the titrant is added, it begins to neutralize the analyte. The decrease in theanalyte concentration changes the . At the equivalence point, equivalent quantities of acid and base have been mixed together such that the acid-basereaction is complete, and the is determined by the product. In the case of a strong acid-strong base titration, the salt formed is neutral, and . In aweak acid-strong base titration, a basic salt is produced, and . In a weak base-strong acid titration, the salt is acidic, and . After theequivalence point, the is determined by the concentration of excess titrant.