anode
electrode where the oxidation half-reaction takes place
battery
galvanic cell in which the electrical work is used as a source of electrical power
cathode
electrode where the reduction half-reaction takes place
cathodic protection
method of protecting a metal by sacrificing another metal as an anode in a galvanic cell
circuit
path through which electrons flow
corrosion
process by which metals oxidize and return from a reduced form to their natural oxidation state
dry cell
galvanic cell in which the electrolytes exist as pastes
electric current
flow of electric charge
electric potential
amount of work required to move one charged particle from one point to another
electrical work
voltage between two points when a charged particle is moved between them
electrochemistry
branch of science that studies chemical reactions that cause electrons to move, resulting in the transfer of electrical charge
electrode
electrical conductor through which current enters or leaves an electrochemical cell
electrolysis
process of using electric current to do work on a chemical cell against its electric potential
electrolyte
ionic solution that can be decomposed by electricity
electrolytic cell
electrochemical cell that requires electrical energy to drive a nonspontaneous redox reaction
Faraday constant
charge of one mole of electrons (96,485 C/mol)
fuel cell
device that generates electrical power through the ionization of hydrogen or another molecule
galvanic cell
electrochemical cell formed when metal strips connected by a wire are immersed in different solutions of a redox reaction and the solutions are connected by a salt bridge
galvanic cell notation
shorthand method of describing the setup of a galvanic cell
galvanization
process that coats a metal with zinc as a sacrificial anode
inert electrode
electrode that does not take part in a chemical reaction but serves only to transfer electrons
Nernst equation
equation used to find the cell potential under conditions that are not standard, given as
oxidation half-reaction
half-reaction showing oxidation (electron loss) of a species
reduction half-reaction
half-reaction showing reduction (electron gain) of a species
sacrificial anode
anode made of a metal coupled to a more valuable metal, which it protects as part of a galvanic cell that undergoes galvanic corrosion
salt bridge
inert connection between the two half-cells, composed of either a glass tube filled with an inert salt solution or a strip of filter paper soaked in an inert salt solution, that transfers ions between the half-cells
standard cell potential
potential difference between the cathode and the anode under standard conditions
standard hydrogen electrode (SHE)
platinum electrode in 1 M H+(aq) solution with bubbled hydrogen gas at 1 atm of pressure
standard reduction potential (E°)
tendency of the species to be reduced under standard conditions