amplitude
height of a wave, measured as the distance from the point of equilibrium to a crest or a trough
Aufbau principle
principle that states that electrons fill orbitals in order of increasing energy
de Broglie hypothesis
idea that matter may behave as a wave
de Broglie wavelength
wavelength () of a particle having mass m and traveling at velocity v using Planck's constant, h; given as
degenerate orbital
one of two or more orbitals with the same energy
electromagnetic radiation
wave of energy produced by the movement of particles through space
electromagnetic spectrum
entire range of electromagnetic waves, defined by their energy, wavelengths, and frequencies
electron configuration
orbital filling of electrons in an atom based on their quantum numbers in increasing energies
electron orbital
area of an atom in which an electron has the greatest probability of being located. Each orbital can contain at most two electrons.
electron shell
one or more electron subshells that have the same quantum number
electron subshell
group of electron energy levels with the same size and shape that have the same quantum numbers and
excited state
electron state that has a higher energy level than the lowest energy state (ground state)
frequency
number of oscillations of a wave that occur in a given period of time, usually a second, measured in hertz (Hz)
ground state
electron state that is lowest in energy
Heisenberg uncertainty principle
principle that it is impossible to simultaneously measure the position and the momentum of a particle
Hund's rule
rule that states that when filling degenerate orbitals (for example, the 3p orbital), electrons must first singly occupy all the empty orbitals in the subshell before pairing within the same orbital
line spectrum
pattern of colors on a dark background produced by an element when it gives off light (emission) or a pattern of dark lines on a background of the electromagnetic spectrum produced by an element when it absorbs light (absorption)
node
point on a standing wave that stays fixed and does not oscillate
Pauli exclusion principle
principle that states that paired electrons may never have the same spin value, which means they cannot have the same four quantum numbers
photoelectric effect
emission of electrons when light strikes a material
photon
fundamental particle that has a fixed amount of energy stored as electromagnetic radiation
Planck's constant (h)
; describes the ratio of energy to frequency of a photon
quantized
exists only as discrete values
quantum mechanics
branch of science that deals with subatomic particles, their behaviors, and their interactions
quantum number
one of four numbers, , , , and , that together describe the orbital state of subatomic electrons
wave
periodic oscillation of energy or matter
wave function
mathematical expression that gives information about measurable properties of a system, such as energy, momentum, and position
wave-particle duality
having properties of both particles and waves
wavelength
distance between two identical parts of a wave