adhesive force
attraction between unlike molecules, such as forces between a liquid and its container
amorphous solid
solid composed of particles that are not organized into a crystalline pattern
boiling point
temperature at which a substance changes from a liquid to a gas at constant temperature and pressure
capillary action
ability of a liquid to move up a tube against other forces, such as gravity and intermolecular interactions, including surface tension and cohesion
cohesive force
attraction between the same type of molecules
condensation
phase transition from gas to liquid at a constant temperature and pressure
covalent solid
crystalline solid formed from a network of atoms joined by covalent bonds
critical pressure
minimum pressure required for condensation of a gas at its critical temperature
critical temperature
temperature above which a gas cannot become a liquid
crystalline solid
solid in which the particles repeat at regular intervals in an ordered crystalline lattice
deposition
phase transition from gas to solid
enthalpy (H)
internal energy of a system plus the work needed to displace the environment to produce the components of the system
freezing
phase transition from liquid to solid at a constant temperature and pressure
ionic solid
solid held together by electrostatic forces between positively and negatively charged ions
lattice
atoms, ions, or molecular fragments arranged in three-dimensional space
liquid
state of matter that has a definite volume but not a definite shape, consisting of particles that are close together and freely flow
melting
phase transition from solid to liquid at a constant temperature and pressure
melting point
temperature at which a substance changes from a solid to a liquid at a constant temperature and pressure
metallic solid
solid composed of atoms held together by metallic bonds
molecular solid
crystalline solid held together via van der Waals intermolecular forces
simple cubic unit cell
unit cell that forms a six-sided box with with a fourth (1/4th) of an atom, ion, or molecule located at each corner
solid
state of matter that has a definite volume and a definite shape, consisting of particles that are closely packed and move only by vibrating
sublimation
phase transition from a solid to a gas at a constant temperature and pressure
supercritical fluid
substance that has properties of both a liquid and a gas at a temperature and pressure above the critical point
surface tension
tendency of a liquid surface to acquire the smallest possible surface area and resist outside forces, such as cohesive and intermolecular forces
unit cell
simplest repeating arrangement of particles, such as atoms, molecules, or ions, within an ordered crystal
vapor pressure
pressure exerted by a vapor in equilibrium with its solid or liquid form in a closed system
vaporization
phase transition from liquid to gas at a constant temperature and pressure
X-ray crystallography
method of determining the arrangement of atoms in a crystal using X-rays