Metals, Metalloids, and Nonmetals

Metalloids

There are seven metalloids: boron (B), silicon (Si), germanium (Ge), arsenic (As), antimony (Sb), tellurium (Te), and polonium (Po). Metalloids have electronegativity values between those of metals and nonmetals. Metalloids behave like metals in some conditions and like nonmetals in others. In certain conditions, it is possible to combine advantages of both metals and nonmetals in metalloids.

Metalloids are a group of seven elements found between the metals and nonmetals on the periodic table. Metalloids share some characteristic properties of metals, such as metallic luster. They also share properties of nonmetals: they generally do not conduct electricity as well as metals and they tend to be brittle. Metalloids have electronegativity values that range between those of metals and nonmetals. This intermediate electronegativity is the reason that metalloids behave similarly to both metals and nonmetals.

Silicon and boron exhibit characteristic bonding behavior and have many practical applications due to the way they interact with oxygen. A silicon-silicon bond is not particularly strong. On the other hand, a silicon-oxygen bond is quite strong. A mineral that contains both silicon and oxygen is a silicate. Silicates can grow to be enormous molecules by alternating the silicon and oxygen atoms. Rocks, sand, and clay are mostly made up of silicates. Glass is another example of a silicate.

A solid material with more than one possible structure is a polymorph. An example of a polymorph is silica. It forms the basis of many common minerals and can appear in different forms. Both sand and quartz are minerals that are made mostly of silica. The orthosilicate ion (SiO44–) is the basis of many silicate minerals. Orthosilicate has a tetrahedral shape consisting of one silicon atom and four oxygen atoms. Two orthosilicate ions can be connected by an oxygen atom, forming a disilicate ion (Si2O76–). The disilicate ions can be connected to each other to form a chain, a sheet, or a three-dimensional shape. When each orthosilicate ion connects to four other orthosilicate ions, a three-dimensional chain solid is formed. Because each orthosilicate is connected to four others by an oxygen atom, the net formula of the compound becomes silica (SiO2).

Orthosilicate Ion, Silicate Chain, and Silicate Sheet

Orthosilicate ions form disilicate. Disilicate ions can be connected to each other to form chains, sheets, or three-dimensional structures.

Silica Minerals

Both sand and quartz are made from silica.
Silica can be melted, which breaks down many of the silicon-oxygen bonds, and made into glass. But if the liquid is cooled too rapidly, the atoms cannot order themselves into a proper crystalline structure. The result is an amorphous solid, a solid composed of particles that are not organized into a crystalline pattern. Another metalloid is boron. Boron is used to change properties of other materials and is used as an additive in fiberglass and ceramics. Pure boron has two forms. It can be either a solid hard crystal or amorphous brown powder at room temperature. Boron has three valence electrons. Its oxidation state is +3 in most stable compounds. Boranes are compounds that contain only boron and hydrogen. When boron bonds with three hydrogen atoms borane (BH3) is formed. This compound has six valence electrons. Boranes can further react with another borane to form diborane (B2H6). In diborane, two of the hydrogen atoms form a bond with each boron atom, bridging them.
Diborane is an unusual molecule in which some of the hydrogen atoms are bonded to two other boron atoms.
A borate is an ion with boron-oxygen bonds. The simplest borate is orthoborate ([BO3]3– ). More complex ions have multiple boron and oxygen atoms. A tetraborate anion, for example, has the formula [B4O7]2–. Borax, the most commonly used borate salt, has the formula Na2B4O7·10H2O. Boron occurs naturally and can be found in dry lake deposits where lakes have had repeated evaporation. The boron is mined from these deposits and is often used to prepare other boron compounds.
An orthoborate anion has a trigonal planar structure.