absolute zero
minimum possible temperature theoretically achievable, equal to 0 K (–273.15°C), at which there is no particle motion
entropy (S)
measure of the disorder of a system
equilibrium
state in which the forward and reverse reactions are equal
first law of thermodynamics
law that states that energy cannot be created or destroyed, only transformed from one type of energy to another type of energy; given as
free energy
capacity of a system to do work
Gibbs free energy (G)
amount of work done by a system, expressed as , where H is enthalpy, T is temperature, and S is entropy
macrostate
measurable macroscopic properties of a system
microstate
possible energy and positional configuration of the particles of a system
nonspontaneous change
process in which energy must be added to the system for the change to occur
second law of thermodynamics
law that states that the total entropy of an isolated system only increases over time
spontaneous change
process in which energy is released as a system changes
standard entropy (S°)
entropy of one mole of a substance under standard state conditions, expressed in units J/(K mol)
standard state
set of specific conditions under which reactions are measured, typically 0°C and 1 atm pressure
thermodynamics
branch of physical science that investigates the energy and work of systems
third law of thermodynamics
law that states that the total entropy of a system approaches zero as the temperature of the system approaches absolute zero
work (w)
energy that is transferred when a force acts on an object over a distance
zeroth law of thermodynamics
law that states that when two thermodynamic systems are in thermal equilibrium with a third system, they are in thermal equilibrium with each other