alcohol
hydrocarbon containing a hydroxyl functional group
carbonyl
functional group in which a carbon atom is double-bonded to an oxygen atom
dehydration
removal of water from a compound
Dess-Martin oxidation
oxidation of a primary alcohol to produce an aldehyde or a secondary alcohol to produce a ketone using Dess-Martin periodinane (DMP)
diol
alcohol with one additional hydroxyl group
Grignard reagent
reagent that has the formula RMgX, where the halogen may be , , or
hydration
addition of a water molecule as and to two adjacent carbon atoms
hydroboration-oxidation
chemical reaction that creates products with an anti-Markovnikov orientation with the hydroxyl group attached to the carbon with the least-substituted carbon
hydrogen bond
weak intermolecular bond between a hydrogen atom of one molecule and a highly electronegative atom (usually fluorine, oxygen, or nitrogen) of a nearby molecule
intermolecular force
attractive or repulsive force between a molecule and a nearby molecule, atom, or ion
organometallic
compound that contains a metal bonded directly to a carbon
organometallic reactions
nucleophilic addition reaction reaction with an organometallic reagent
oxidation
reaction that involves the removal of an electron from an atom
oxymercuration-demercuration
chemical reaction that creates a Markovnikov product through the addition of mercuric acetate (Hg(OAc)2) and water followed by a reducing agent
phenol
benzene ring where a bond is substituted for a hydroxyl group, giving a unit
protecting group
group used in chemical synthesis to briefly mask the characteristic chemistry of a functional group so it will not interfere with a reaction
pyridinium chlorochromate oxidation
oxidation of a primary alcohol to produce an aldehyde or a secondary alcohol to produce a ketone using pyridinium chlorochromate (PCC)
reduction
reaction that involves the addition of an electron to an atom
substitution
chemical reaction where one functional group is replaced with another functional group
Swern oxidation
oxidation of a primary alcohol to produce an aldehyde or a secondary alcohol to produce a ketone using dimethyl sulfoxide (DMSO) and oxalyl chloride followed by addition of an organic base such as triethylamine