alcohol
hydrocarbon containing a hydroxyl functional group
aldehyde
organic compound that contains a carbonyl group () bound to one alkyl () fragment and one hydrogen atom, with or stoichiometry
carbonyl
functional group in which a carbon atom is double bonded to an oxygen atom
demercuration
second step in the hydration of alkenes, where the acetoxymercury group is reduced with sodium borohydride to a hydrogen atom
Dess-Martin periodinane
aromatic reagent that contains a cyclic ring with a pentavalent (five-bonded) iodine
electronics
charge or electrical factors that influence an atom or molecule
keto-enol tautomerism
chemical equilibrium between a ketone or aldehyde and an enol
ketone
organic compound that contains a carbonyl group () bound to two alkyl () fragments (which are the same, R and R, or different, R and R′) with or RCOR′ stoichiometry
mercurinium
positively charged mercury ion
oxidation
reaction that involves the removal of an electron from an atom
oxymercuration
reaction of an alkene with mercury(II) acetate in aqueous THF to form a three-membered mercurinium ion
ozonolysis
cleavage of an alkene, alkyne, or azo group with ozone
primary alcohol
alcohol with a hydroxyl group attached to a carbon that also has two hydrogen atoms attached to it
reduction
reaction that involves the addition of an electron to an atom
secondary alcohol
alcohol with a hydroxyl group attached to a carbon that also has only one hydrogen atom attached to it
sterics
size, arrangement, and spatial factors that influence an atom or molecule
Swern oxidation
mild method of converting a primary alcohol into an aldehyde without the use of chromium reagents
tautomer
one of two or more constitutional isomers that differ only in the placement of a single proton