annulene
any of a class of completely conjugated cyclic hydrocarbons (such as benzene or cyclooctatetraene) that are monocyclic
antiaromatic
molecule that is cyclic, has a continuous circle of p orbitals, has planar geometry, and does not have a Hückel number of electrons but instead has [4n] electrons
aromatic
molecule that is cyclic, has a continuous circle of p orbitals, has planar geometry, and has a Hückel number () of electrons
benzene
cyclic aromatic molecule with the chemical formula C6H6
derivative
compound that is derived from a similar compound by a chemical reaction
disubstituted derivative
derivative of benzene with two substituents
Frost circles
method to predict bonding molecular orbitals, which indicate aromaticity
Hückel's rule
rule that states that the number of delocalized electrons in the cloud in an aromatic ring is equal to [], where n is zero or a positive integer
heterocyclic
any molecule relating to, characterized by, or being a ring composed of atoms of more than one kind
infrared (IR) spectroscopy
method that observes the vibrations of bonds and provides evidence of the functional groups present
meta
prefix that indicates there is one carbon atom between the carbon atoms that have the substituents, producing a 1,3-disubstituted benzene pattern
molecular orbital theory
solution of the Schrödinger equation that describes the probable location of an electron relative to the nuclei in a molecule and so indicates the nature of any bond in which the electron is involved
monosubstituted derivative
derivative of benzene with only one substituent
nonaromatic
molecule is not cyclic or planar or does not have a continuous circle of p orbitals
ortho
prefix that indicates there are no carbon atoms between the carbon atoms that have the substituents, producing a 1,2-disubstituted benzene pattern
para
prefix that indicates there are two carbon atoms between the carbon atoms that have the substituents, producing a 1,4-disubstituted benzene pattern
polycyclic
refers to molecules with more than one ring structure
polycyclic aromatic compound
compound that has more than one ring structure and is aromatic
polysubstituted derivative
benzene with more than two substituents
resonance
method that organic chemists use to depict the Lewis structures of organic molecules where electrons can be in two or more different places around fixed atoms