chromatography
technique or series of techniques for separating a mixture into its components
electron impact
method for producing positive ions in mass spectrometry, resulting from bombardment of a molecule with high-energy electrons
electrospray ionization
technique used in mass spectrometry to produce ions by applying a high voltage to a liquid to create an aerosol
exact molecular mass
actual mass of a molecule calculated to four decimal places and obtained by high-resolution mass spectrometry
fragmentation
dissociation of a molecule because of high-energy impact in mass spectrometry
fragmentation pattern
pattern of ions produced by fragmentation of the molecular ion during mass spectrometry
gas chromatography
analytical method in which a compound is vaporized and separated into its components
high-resolution mass spectrometry
mass spectrometry method that allows for precise measurement of a molecule's mass
liquid chromatography
analytical method in which a compound dissolved in a solvent is separated into its components
m/z ratio
ratio of an ion's mass (m) to its charge (z)
M+ + 1 peak
peak on a mass spectrum that is used to determine the number of carbon atoms in a molecule
M+ peak
peak on a mass spectrum indicating the molecular ion, sometimes called the parent ion
mass spectrometry
analytical method in which a molecule is ionized and the resulting fragments and ions are analyzed
matrix-assisted laser desorption/ionization (MALDI)
mass spectrometric method used in determining the amino acid sequence of larger biomolecules
McLafferty rearrangement
reaction in which a molecule containing a keto group breaks apart and an H atom transfers from one fragment to another
molecular formula
formula indicating the number of atoms of each type of element in a molecule
molecular ion
ion formed by removal or addition of an electron without compromising the molecular structure
nominal molecular mass
sum of the mass numbers of a molecule's constituent atoms