1H nuclear magnetic resonance spectrum
plot that has the radio frequency on the -axis and the signal or amount of energy on the -axis
3-D nuclear magnetic resonance
spectrum that plots the signals from three different nuclei against one another in three-dimensional space
alpha state
energy state that is parallel to a field and requires lower energy
beta state
energy state that is antiparallel to a field and requires higher energy
chemical shift
difference in the resonant frequency of two protons because of their environment
correlation spectroscopy
plot where both axes are from proton NMR and they are plotted against one another to show which protons are coupled to each other
deshielded
characteristic of protons near highly electronegative nuclei in which the protons experience more of the magnetic field
deuterated
characteristic of a compound in which a hydrogen atom is replaced with a deuterium atom that has one proton and one neutron as compared to hydrogen that does not have any neutrons
deuterated solvent
liquid that is used to dissolve other substances (a solvent) that has at least one of its hydrogen atoms replaced with a deuterium atom that has one proton and one neutron as compared to hydrogen that does not have any neutrons
deuterium
isotope of hydrogen that contains one proton and one neutron
diastereotopic
characteristic of hydrogen atoms that are not in the same chemical environment and produce different signals in NMR spectroscopy
distortionless enhancement of polarization transfer C-NMR
technique that provides the number of protons bonded to each carbon as well as the chemical shift provided by a regular carbon nuclear magnetic resonance (13C NMR)
downfield
left part of the NMR spectra where a low field strength is applied
enantiotopic
characteristic of hydrogen atoms that are not in the same chemical environment and produce different signals in a chiral environment, such as in chiral solvents in NMR spectroscopy
heteronuclear correlation spectroscopy
1H NMR spectra plotted on one axis with 13C spectra plotted on the other axis
homotopic
characteristic of hydrogen atoms that are in the same chemical environment and produce the same signal in NMR spectroscopy
integration
intensity of the signal on a proton nuclear magnetic resonance (1H NMR) spectrum, providing a ratio of the number of protons found in the signal
nuclear magnetic resonance
resonance that occurs when atomic nuclei that have spin are placed into a magnetic field. Individual spins that are normally random in orientation line up parallel to the magnetic field.
nuclear magnetic resonance spectrometer
instrument that uses the magnetic moment to gain information about the structure of a compound
nuclear spin
magnetic moment resulting from the total angular momentum of certain nuclei, such as those with an odd number of either protons or neutrons
nucleon
proton or neutron in an atomic nucleus
shielded
characteristic of protons that not experience the full effect of the magnetic field because of the electrons surrounding them
split
characteristic of a signal that has multiple peaks of different areas and heights
upfield
right part of the NMR spectra where a high field strength is applied