Solutions to Homework Problems in UPC Chapter 8
March 12, 2015
(Continuation of the solution to problem 8)
e) For an 1s electron the quantum numbers are S = 1/2, L = 0, J = 1/2, so the term symbol is
Final Exam
CHEM 374
Prof. Ben-Amotz
May 4, 2015
Name:
CRIB
Your exam should contain 5 numbered pages (including this page)
plus additional pages containing supplementary information.
FOR FULL CREDIT Y
Solutions to Homework Problems in UPC Chapter 9
April 2, 2015
4a) For the H + H + H2+ , the Huckel secular determinant pertaining to the product H+
2 is
E
=0
E
which is equivalent to ( E)2 2 = ( E +
Solutions to Homework Problems in UPC Chapter 9
April 13, 2015
b = E is
7a) The matrix expression for H
ca
ca
1
=E
=E
cb
cb
0
b E = 0
This also implies that H
E
E
ca
cb
0
1
=0=
0
0
ca
cb
In order
Solutions to UPC Chapter #10
April 30, 2014
1) The number of thermally accessible states is given by the partition function.
For N2 , we have ( = 2):
T
300 K
qr =
=
52
r
2(2.9 K)
For CO ( = 1):
qr =
5a)
KN = Kc =
t
r
(qHD
qHD
)2
t
r
t
r
qH2 qH2 qD2 qD
2
=
3/2
mHD
HD R
HD
3/2
mH
2
H2 R
H2
2
3/2
mD
=
2
D2 R
D2
3/2
mHD
HD /HD
3/2
mH
2
H2 /H2
2
3/2
mD
2
D2 /D2
Note that since the units all cancel, th
Chem 37401
Spring 2016
Laser Raman Spectroscopy
Introduction
Lasers today play an enormous role in physical chemistry. Very often, weak, sometimes
non-linear, interactions of light with matter provide