Florida Institute of Technology Chemical Engineering Department
CHE-3110 Chemical Engineering Thermodynamics Spring 2014
Homework #2 Solution
Problem # 1:
Consider the system shown in the figure. Tank A has a
volume of 100 [L] and contains saturated vapor
Florida Institute of Technology Chemical Engineering Department
CHE-3110 Chemical Engineering Thermodynamics Spring 2015
Homework #1 Solution
Problem # 1:
Consider a piston-cylinder arrangement in which a frictionless piston is free to move between two
se
Florida Institute of Technology 0 Chemical Engineering Department
CHE-3110 0 Chemical Engineering Thermodynamics I Spling 2014
1 L:- _-,-';- ._ i - ID#:xxx—Xx-
Exam 1 0 Section 1
[Books and Notes Closed]
Problem 1 (15 points): Give deﬁnitions to the f
Florida Institute of Technology Chemical Engineering Department
CHE-3110 Chemical Engineering Thermodynamics Spring 2015
Homework # 3 Solution
Problem # 1:
Calculate the pressure inside a 61.19 L tank containing 1 kg of an equimolar mixture of
ethane (1)/
Florida Institute of Technology Chemical Engineering Department
CHE-3110 Chemical Engineering Thermodynamics Spring 2014
Homework #1 Solution
Problem # 1:
Consider a piston-cylinder arrangement in which a frictionless piston is free to move between two
2
Florida Institute of Technology Chemical Engineering Department
CHE-3110 Chemical Engineering Thermodynamics Spring 2015
Homework # 3 Solution
Problem # 1:
Calculate the pressure inside a 61.19 L tank containing 1 kg of an equimolar mixture of
ethane (1)/
Florida Institute of Technology Chemical Engineering Department
CHE-5110 Equilibrium Thermodynamics Fall 2016
Lecture Problems September 7th, 2016
Problem #2:
Consider a piston-cylinder arrangement shown in the figure. The piston mass is such that 275
kPa
Florida Institute of Technology Chemical Engineering Department
CHE 5110 Equilibrium Thermodynamics Fall 2016
Lecture Notes September 9th, 2016
First Law of Thermodynamics Open System
In a closed system the mass within the system is constant. The First La
CHE-5110 Equilibrium Thermodynamics Formula Sheet - Review
_
Dimension: Defines qualitatively a physical entity that could be observed or measured. Example: length,
time, mass, etc
Units: Means of expressing the dimensions. Example: ft, cm, kg, lbf.
Units
CHE-5110 Equilibrium Thermodynamics Formula Sheet
_
Equation of State:
Ideal Gas:
f (P v T ) = 0
Pv = RT
or
PV = nRT
for Ideal Gases:
Cp = Cv + R
Virial Equation of State:
Virial Equation in v:
nd
rd
th
where, B, C, D are the 2 , 3 , and 4 virial coeffici
\ F l n'cal Engim
armodynamit
Z; Name:
Exam 1 0 Section 1
[Books and Notes Closed]
Problem 1 (15 points): Give deﬁnitions to the following terms:
1.1. P-V diagram for a gal substance. Give as much information as you can
it 1" mm- the 595% on; gar Gu’?
’wmical Engi:
rmodynamics 0
Exam 2 0 Section 1
[Books and Notes Closed]
Problem #1 (15 points): Give deﬁnitions to the following terms:
W. Isopleths
Lamp Qré g onstmt” COM‘SF‘QZD’: MU)?
\, Aqégm m M M _ E.
/
1.2. Critical
Florida Institute of Technology 0 Chemical Engineering Department
CHE-5110 0 Equilibrium Thermodynamics 0 Fall 2016
Lecture Problem 0 September 12th, 2016
Problem # 1:
The rigid tank A shown in the gure, contains 5 kg of steam at 800 kPa and 300 C. The
Florida Institute of Technology Chemical Engineering Department
CHE-5110 Equilibrium Thermodynamics Fall 2016
Lecture Wednesday, August 31st, 2016
First Law of Thermodynamics: Closed System
In a closed system the mass within the system is constant. The Fi
Florida Institute of Technology Chemical Engineering Department
CHE-2101 Chemical Engineering Fundamentals I Fall 2016
Lecture Notes August 26, 2016
Pure Component Fluids Behavior:
Phase: A completely homogeneous and uniform state of matter, e.g. solid, l
Florida Institute of Technology Chemical Engineering Department
CHE-3110 Chemical Engineering Thermodynamics Spring 2015
Lecture Problem January 23rd, 2015
Problem # 1:
A cylinder fitted with a frictionless piston contains water as shown in the
figure. Th
CHE-3110 ChE Thermodynamics Practice Problems 01/28/2015
_
Calculations with Heat Capacity Cp
Example:
A ternary mixture of n-butane (1)/ n-pentane (2)/ carbon dioxide (3) with the following
composition C4 (1) 0.3, C5 (2) 0.4, and CO2 (3) 0.3 is heated fr
USE OF THERMODYNAMIC TABLES
Given T, P, or V determine the state of the substance. (Speciﬁc Vollnne “v” is used in
these examples, but the method can be applied to h, u, and s).
1- GivenT,P 9 v ‘
1a. Assume T = T53;
Go to Table A1. — Saturated Steam: Temp
Florida Institute of Technology Chemical Engineering Department
CHE-3110
Chemical Engineering Thermodynamics Spring 2015
Problem April 15th, 2015
Problem:
For a gaseous equimolar mixture of CO2 (1)/propylene (2), find the Gibbs Free Energy at
25 [ C] and
Florida Institute of Technology Chemical Engineering Department
CHE-3110 Chemical Engineering Thermodynamics Spring 2015
Lecture Problem January 21st, 2015
Problem # 1:
The rigid tank A shown in the figure, contains 5 kg of steam at 800 kPa and 300 C. The
Florida Institute of Technology Chemical Engineering Department
CHE-3110 Chemical Engineering Thermodynamics Spring 2014
Problem April 11th, 2014
Problem:
For a gaseous equimolar mixture of CO2 (1)/propylene (2), find the Gibbs Free Energy at
25 [C] and 3
Florida Institute of Technology Chemical Engineering Department
CHE-3110 Chemical Engineering Thermodynamics Spring 2014
Lecture Problems April 16th, 2014
Partial Molar Properties
Problem # 1:
Suppose for a given T and P that the composition dependence of
Florida Institute of Technology Chemical Engineering Department
CHE-3110 Chemical Engineering Thermodynamics Spring 2014
Lecture Problems April 21st, 2014
Problem # 1:
The enthalpy of a binary liquid system of species 1 and 2 at fixed T and P is represent
Florida Institute of Technology Chemical Engineering Department
CHE-3110 Chemical Engineering Thermodynamics Spring 2014
Lecture Problem March 28th, 2014
Problem # 1:
A rigid tank having a capacity of 27.5 L, contains 0.5 kg of a gaseous mixture of
ethane
CHE-3110 Chemical Engineering Thermodynamics Formula Sheet
_
Thermodynamic Reactions for a Homogeneous Closed System
H = U + PV
A = U TS
G = U + PV TS = H TS = A + PV
Fundamental Equations
dU = TdS PdV
dH = TdS + V dP
dA = -S dT P dV
dG = -S dT + V dP
Ext
Florida Institute of Technology Chemical Engineering Department
CHE-3110 Chemical Engineering Thermodynamics Spring 2013
Homework #5 Solution
Problem:
For a gaseous equimolar mixture of CO2 (1)/propylene (2), find the Gibbs Free Energy at
25 [C] and 30 at
Florida Institute of Technology Chemical Engineering Department
CHE-3110 Chemical Engineering Thermodynamics Spring 2013
Practice Problem April 17th, 2013
Partial Molar Properties
Problem # 1:
Suppose for a given T and P that the composition dependence of
CHE-3110 Chemical Engineering Thermodynamics Formula Sheet
_
Review Concepts:
Dimension: Defines qualitatively a physical entity that could be observed or measured. Example:
length, time, mass, etc
Units: Means of expressing the dimensions. Example: ft, c