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The synthesis of carbohydrates can be particularly difcult because crf the large number Df chiral eenters and {JH functional grc-ups present....

The synthesis of carbohydrates can be particularly difficult because of the large number of chiral centers and  functional groups present. Epoxides can be useful synthetic intermediates in carbohydrate syntheses. Draw the product of the following reactions of a Gilman reagent with each epoxide.


a) What is the configuration of the chiral carbon in the epoxide? What is the configuration of that carbon after the reaction? Are any new chiral centers created as a result of the reaction?


Screen Shot 2018-04-04 at 10.23.28 PM.png

Screen Shot 2018-04-04 at 10.23.28 PM.png

15.25. The synthesis of carbohydrates can be particularly difficult because crf the large number
Df chiral eenters and {JH functional grc-ups present. Epexides can be useful synthetic
intermediates in carbuhydrate syntheses. Draw the prdduct of the fulluwing reactions of a Gilman reagent with each epc-Jdde. {a}
Q, DH 1. HrfiluLi
i-Zlh
l"ilk/{\J/l -+ll'L'-'{:
“u —-I'
3- FQIJ'. IIEI Q] G I. 31-11,! mu
a» Elm-r
-: " —Tfl-"‘f.i —1Il'{:
um, u m 5!. Hill. IIEI

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