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List Number:_______ (Check your list number on MOODLE) Thanks! Chem 2261 Sp13 Homework 2 Name:________________ (Due March 14th, 9 AM) No Exceptions,...

This is the homework for my Organic Chemistry course. I just completed it, but would love to check my work before I hand it in.
List Number:_______ (Check your list number on MOODLE) Thanks! Chem 2261 Sp13 Homework 2 Name:________________ _______________ (Due March 14th, 9 AM) No Exceptions, No Excuses Last Name First Name 1. Draw the most stable conformation of the following molecules. You MUST DRAW the Hydrogens that are directly connected to each one of the projections ( 3 points ) a) 3,3-dichloro-6,6-dimethyloctane b) cis-1-butyl-4-neopentylcyclohexane (looking along C4-C5) 2. Label the following molecules R or S accordingly: ( 2 points ) O OH CH 3 C OH H CH 3 F H N 3. Draw Fischer projections for the stereoisomers of 2,3-dichloro-2-fluorobutane. Keep the carbon chain vertical and start labeling from the top. ( 2 points ) 1
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4. Give an acceptable IUPAC name for the following molecule: ( 2 points ) molecule A ( include R and S ) Cl Br Name of A :_________________________________________________________________________ 5. In the following reaction: a) Show a detailed arrow pushing mechanism. ( 2 points ) b) Draw the product(s) using Fischer representation. Keep the carbon chain vertical and start labeling from the top ( 1 point ) c) From the following options circle the one that describes the product(s). ( 0.5 points ) Single Chiral Product Racemic Mixture Pair of Diastereomers A Meso Compound Single Achiral Product with No Chiral Centers d) Circle the appropriate optical activity of the product(s): ( 0.5 points ) Optically active Optically Inactive Do not use these structures. Redraw them below and show every step. If an intermediate is common draw it twice!!! C C CH 3 CH 2 H CH 3 H + Br 2 2
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