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The question is in the pic attached, please provide detailed solutions 

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cell potential for mno4.docx

Answer First of all, write the overall cell reaction.
Oxidation:- Mn2+ + 12H2O MnO4- + 8H3O + 5e…………….multiply by 4
Reduction:- O2 + 4H3O + 4e 6H2O………………….multiply by 5...

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