MEE 6501, Advanced Air Quality Control
2
UNIT x STUDY GUIDE
Title
efficiencies for smaller particles, the propensity for erosion of components due to abrasive actions of particles,
and the large space required to accommodate the equipment (Phalen & Phalen, 2013; Godish et al., 2015).
Electrostatic precipitators (including mist precipitators) are designed to operate at high temperatures while
creating moisture-laden air as the capture medium. This makes electrostatic capture very efficient for very fine
particles. The advantages include the compact nature of the equipment, the lack of dust generation during the
capture process, and the constant pressure drop to the system during particle capture. Still, among the most
significant disadvantages of the design are the large space requirements for the equipment, the relatively
higher initial costs, and the phenomena of some pollutant particle charges not being matched well enough to
the system for efficient capture (Phalen & Phalen, 2013; Godish et al., 2015).
Filtration options include traditional filtration systems (such as medium filters) that are excellent for capturing
dust, fumes, and non-sticky particles with a wide disparity of sizes. This makes for highly efficient systems,
moderate power requirements, and a nice, dry disposable waste. However, the low initial cost is often offset
by higher bag replacement costs (such as replacing entire bag houses during maintenance shutdowns), and
the potential for fire hazards seem to be intrinsically higher in these designs (Phalen & Phalen, 2013; Godish
et al., 2015).
More advanced filtration options include spray chambers and wet scrubbers (to include venturi scrubbers and
wet cyclones). These afford very small particle capture, constant pressure drop (not unlike electrostatic
precipitators), and no dust generation. But, one of the disadvantages of the design is that the process
involves water. As such, the wastewater generated from the process creates another waste stream that must
be handled properly for pre-treatment and ultimate disposal (Phalen & Phalen, 2013; Godish et al., 2015).
According to your textbook, gas-phased pollutant capture strategies include a few more options than PM
capturing. These include thermal oxidizing (thermal oxidizers, flaring, and catalytic systems), adsorption
(packed sorbent beds), absorption (scrubbing), and biological treatment. The different options available within
each of these strategies afford the air engineer to aptly match the diverse types of gas pollutants to the
control.
Thermal oxidizers or “afterburners” are gas combustion chambers with temperatures typically ranging 540ºC
to 815ºC. These systems are robust enough to accommodate a moderate range of gases and work similarly
to a flare in terms of simply combusting the gas mixtures into less complex gases. There is normally very little
maintenance requirements for this technology, and the process is very efficient. However, as with any
combustion-related process, carbon dioxide (CO
2
) and carbon monoxide (CO) is still a potential outcome as a
byproduct of combustion (Phalen & Phalen, 2013; Godish et al., 2015).
Flare systems are typically used specifically for hydrocarbon-rich gases within a range of concentration just
below the upper explosive limit (UEL) and just above the lower explosive limit (LEL). The benefit is that the
explosive gases are combusted, often close to or exceeding 99% efficiency. The disadvantage is that, not
unlike afterburners, natural gas is often used as a prime for the flare system to keep the pilot lit, even while
producing other byproducts of combustion (Phalen & Phalen, 2013; Godish et al., 2015).
Catalytic systems (catalytic oxidizers or catalytic converters) are actually catalyst-filled filters that typically
operate at elevated temperatures between 370ºC to 480 ºC to treat gases at or near the LEL (Phalen &
Phalen, 2013). Benefits include the low maintenance requirements associated with thermal oxidation, as well
as the low system pressure drop that is also indicative of electrostatic precipitators. However, one of the most
routinely leveraged benefits is the use of this technology to reduce the footprint (size) and fuel use of other
systems. Disadvantages include the inefficiencies inherent in the design during colder temperatures, the
strong potential for particles to clog the catalytic converter, and the seemingly growing expense of catalyst
replacement (Phalen & Phalen, 2013; Godish et al., 2015).
Adsorption systems (packed beds) are designed to leverage the adherence (sticking nature) of gas molecules
through the van der Waals attractional force phenomena. These can be through either solid or liquid
adsorption systems. As discussed at length in your textbook, this is often accomplished with solid media
systems by packing beds with various packing media of metal, glass, plastic beads, and activated charcoal in
order to create a sorbent environment for the molecules traveling through the system. The polarity of the
molecules helps to inform the air engineer of the appropriate media to use in the system, targeting the gas
molecules of interest for capture. This specificity of gas molecule targeting is among the benefits of this type
of technology, as well as the relative ease of incorporating higher temperature gases for destruction of
