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Why do the effective magnetic moments at 300Kfor first d-transitionseries metal ions in the gas phase fit best for the small multiplet splitting

Why do the effective magnetic moments at 300K for first d-transition series metal ions in the gas phase fit best for the small multiplet splitting limit , but lanthanide species have effective magnetic moments at 300K that are well fitted by the limiting large multiplet splitting ?

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For 3d transition elements, splitting of different J is small as compared to splitting of... View the full answer

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