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1)Why does K 4 [NiBr 6 ] behave as a simple Curie paramagnet , but K 2 [NiBr 4 ] exhibit complex paramagnetic behavior with a temperature dependent...

1)         Why does   K4[NiBr6]  behave as a simple Curie paramagnet , but

K2 [NiBr4]exhibit complex paramagnetic behavior with a temperature dependent effective magnetic moment .   

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IMG_20190502_121035.jpg

KA[ Ni Brs ]
101
Kg [ Ni Bry ]
Nic 2 +
Octahedral ( do )
Ni 2+\
tetrahedral ( do )
2
00
16 1 1 t
1 1 1/ 16 16 , '`
Do
d 8
16 16 1 1. 1 1 )
VIL AL *^ ^t 2 9
Do > > P ( pairing energy )`
Even...

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