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Chem 202, Fall 2016 Homework Packet 10 (Carboxylic Acid Derivatives) 1 | P a g e Name: Email: FOR ADDITIONAL PRACTICE, PLEASE READ THE BOOK AND DO PROBLEMS IN Chapter 11 # 1- 3, 6-8, 10, 16, 17, 20, 26, 29, 30-32 1. Nomenclature. Give the proper IUPAC name for the following compounds. Place your answer on the line BELOW the structure.
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Chem 202, Fall 2016 Homework Packet 10 (Carboxylic Acid Derivatives) 2 | P a g e 2. Reactivity of Carboxylic Acid Derivatives a. Rank the following carboxylic acid derivatives in order from LEAST reactive to MOST reactive when they undergo nucleophilic acyl substitution reactions: b. Justify your answer thoroughly in words: 3. Fischer Esterification Mechanism : In Chem 203, you will get the opportunity to synthesis Methyl Salicylate, which is known as the scent of Wintergreen! It is a Fischer Esterifcation reaction just like our synthesis of other good smelling scent molecules. Draw the proper FULL electron-pushing mechanism for the reaction below, including ALL intermediates (with formal charges) and electron pushing arrows. Label the Electrophile and Nucleophile in each step! REMEMBER: H 2 SO 4 is an acid CATALYST!
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